26th
74/1
| 1 | Roma | Verona v Roma (Full Time Result) |
26/01/2014 | None | 8/13 | To Run |
| 2 | Sampdoria | Sampdoria v Bologna (Full Time Result) |
26/01/2014 | None | 4/5 | To Run |
| 3 | Torino | Torino v Atalanta (Full Time Result) |
26/01/2014 | None | 3/4 | To Run |
| 4 | Schalke | Hamburg v Schalke (Full Time Result) |
26/01/2014 | None | 6/4 | To Run |
| 5 | Werder Bremen | Werder Bremen v Eintracht Braunschweig (Full Time Result) |
26/01/2014 | None | 4/5 | To Run |
| 6 | Atletico Madrid | Rayo Vallecano v Atletico Madrid (Full Time Result) |
26/01/2014 | None | 2/5 | To Run |
| 7 | Athletic Bilbao | Osasuna v Athletic Bilbao (Full Time Result) |
26/01/2014 | None | 6/5 | To Run |
| 8 | Barcelona | Barcelona v Malaga (Full Time Result) |